Adaptive neural network consensus tracking control for uncertain multi-agent systems with predefined accuracy

Nonlinear Dynamics - This paper proposes the consensus tracking control problem for a class of uncertain nonlinear multi-agent systems. By using a group of nonnegative functions, an adaptive neural...     

通过棒状金属羧酸/羟基次级结构单元形成的锌金属有机骨架的低温余晖性质

通过一个含3个羧基基团的多功能配体2-羟基-1，3，5-苯基三羧酸（HO-H₃BTC）与锌盐构筑了一个三维多孔锌骨架结构配合物，{[Zn₄（O-BTC）₂（H₂O）₅]·2DMF·0.5H₂O}_n（1）。通过单晶X射线衍射、粉末X射线衍射、元素分析、红外光谱、热重分析以及固体紫外吸收光谱对该配合物进行了表征。配合物1是通过棒状金属锌-羧酸/羟基次级结构单元构筑的一个三维骨架结构，其在室温下显示强烈的蓝色荧光。此外，在低温条件下（10 K）配合物1显示余晖性质。     

Preparation and characterization of nickel hydroxide microspheres assembled by nanoribbons

Abstract  

This article describes a facile green strategy for preparing the Ni(OH)₂ microsphere assembled by nanoribbons by the template of the squama inner coat of onion at mild condition. The method is simple and effective. The results of SEM show the products are Ni(OH)₂ microspheres with diameters in the range of 500–2,500 nm. The results of TEM show the microsphere is assembly by nanoribbons, with thickness in the range of 30–50 nm. The products were characterized by powder X-ray diffraction, IR, and thermogravimetric analysis. A possible formation mechanism was also proposed.     

新型膦胺配体羰基钌化合物的合成及其催化性能研究

以十二羰基三钌和o-PPh2C6H4NR2(R=H,Me)配体为原料,成功制备了三种新型羰基钌化合物(μ-o-PPh2-C6H4NH)Ru3(μ-H)(CO)9(2)、(o-PPh2C6H4NH)2Ru(CO)2(3)和(μ-o-PPh2C6H4NMe2)2Ru(CO)3(4).对这三个化合物进行了核磁共振和红外谱学、元素分析和X射线单晶衍射分析表征,并对这三个化合物进行了催化性能研究.化合物2和4可催化苯甲醛加氢反应生成苯甲醇,但是3没有催化活性.从实验角度阐述了膦胺配体钌催化剂的结构与性能关联,进一步探讨了加氢催化反应失活的可能原因.     

One-step synthesis and antibacterial property of water-soluble silver nanoparticles by CGJ bio-template

In this article, a new synthetic method of nanoparticles with fresh Chinese gooseberry juice (CGJ) as bio-template was developed. One-step synthesis of highly water-soluble silver nanoparticles at room temperature without using any harmful reducing agents and special capping agent was fulfilled with this method. In the process, the products were obtained by adding AgNO₃ to CGJ, which was used as reducing agent, capping agent, and the bio-template. The products of silver nanoparticles with diameter of 10–30 nm have strong water solubility and excellent antibiotic function. With the same concentration 0.047 μg mL⁻¹, the antibacterial effect of water-soluble silver particles by fresh CGJ was 53%, whereas only 27% for silver nanoparticles synthesized using the template method of fresh onion inner squama coat (OISC). The excellent water solubility of the products would enable them have better applications in the bio-medical field. The synthetic method would also have potential application in preparing other highly water-soluble particles, because of its simple apparatus, high yield, mild conditions, and facile operation.     

Quantum properties of nonclassical states generated by an optomechanical system with catalytic quantum scissors

A scheme is proposed to investigate the non-classical states generated by a quantum scissors device (QSD) operating on the the cavity mode of an optomechanical system. When the catalytic QSD acts on the cavity mode of the optomechanical system, the resulting state contains only the vacuum, single-photon and two-photon states depending upon the coupling parameter of the optomechanical system as well as the transmission coefficients of beam splitters (BSs). Especially, the output state is just a class of multicomponent cat state truncations at time t=2π by choosing the appropriate value of coupling parameter. We discuss the success probability of such a state and the fidelity between the output state and input state via QSD. Then the linear entropy is used to investigate the entanglement between the two subsystems, finding that QSD operation can enhance their entanglement degree. Furthermore, we also derive the analytical expression of the Wigner function (WF) for the cavity mode via QSD and numerically analyze the WF distribution in phase space at time t=2π. These results show that the high non-classicality of output state can always be achieved by modulating the coupling parameter of the optomechanical system as well as the transmittance of BSs.     

Quartic spline methods for solving one-dimensional telegraphic equations

In this paper, by using a quartic spline in space and generalized trapezoidal formula in time direction, one-dimensional telegraphic equations are solved. We present new classes of two-level schemes. The accuracy of these methods are O(k²+h⁴). It has been shown that by suitably choosing parameter, a high accuracy scheme of O(k³+h⁴) can be derived from our methods. Numerical results demonstrate the superiority of the new scheme.     

[2+2] Cycloaddition of chlorosulfonyl isocyanate to allenyl-sugar ethers

The direction and magnitude of asymmetric induction in the [2+2] cycloaddition of chlorosulfonyl isocyanate to 3-O-allenyl-α-d-xylofuranoses was investigated. It is shown that gem terminal dimethylallenes react more readily than methyl free congeners. The configuration of adducts was established by X-ray and CD-spectroscopy of alkylidene cephams. A stereochemical model of the transition state for the [2+2] cycloaddition of chlorosulfonyl isocyanate and allenyl ethers is proposed, based on the lowest energy conformation of the cumulene.     

奇异摄动反应扩散方程的后验误差估计及自适应算法

研究了一类奇异摄动半线性反应扩散方程的自适应网格方法.在任意非均匀网格上建立迎风有限差分离散格式,并推导出离散格式的后验误差界,然后用该误差界设计自适应网格移动算法.数值实验结果证明了所提出的自适应网格方法的有效性.